4-(4-Nitrobenzenesulfonamido)pyridinium bromide

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4-(4-Nitro­benzene­sulfonamido)pyridinium bromide

In the title compound, C(11)H(10)N(3)O(4)S(+)·Br(-), the benzene ring makes an angle of 88.4 (2)° with the pyridinium ring. The dihedral angle between the nitro group and the benzene ring is 16.5 (2)°. The ions in the crystal structure are linked by a combination of inter-molecular N-H⋯Br and non-conventional C-H⋯Br and C-H⋯O hydrogen bonds, forming a three-dimensional network.

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4-Methoxy­anilinium bromide

The title compound, C(7)H(10)NO(+)·Br(-), consists of almost planar 4-methoxy-anilinium cations, wherein the O atom lies 0.049 (3) Å out of the plane formed by the non-H atoms, and a Br(-) anion. Strong N-H⋯Br and N-H⋯(Br,Br) hydrogen bonding contributes to the stability of the crystal structure and links the cations and anions into a three-dimensional network.

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1-(4-Cyano­benz­yl)-4-methyl­pyridinium bromide

In the title compound, C(14)H(13)N(2) (+)·Br(-), the 1-(4-cyano-benz-yl)-4-methyl-pyridinium cation has a Λ-shaped conformation, and the dihedral angle between the benzene and pyridinium rings is 75.8 (2)°. In the crystal, two cations form a dimer through π-π inter-actions between pyridine rings [the centroid-centroid distance is 3.685 (1) Å].

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4-Cyano­pyridinium bromide

In the title compound, C(6)H(5)N(2) (+)·Br(-), the pyridine N atom is protonated and involved in an inter-molecular N-H⋯Br hydrogen bond which, together with weak C-H⋯N hydrogen bonds, results in the formation of a chain along the c axis. Weak inter-molecular C-H⋯Br inter-actions between pyridine H atoms and Br(-) anions connect these chains into a network parallel to the bc plane.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808035265